| |  | | | | | | | | | 16:00 | Real Madrid-SPA | x | Bayern Munich-GER | 1.86 | 4.05 | 4.07 | |
| | | | | | | | | 19:00 | Huachipato-CHI | x | Gremio/RS-BRA | 3.89 | 3.63 | 1.97 | | | 19:00 | Talleres-ARG | x | Barcelona-ECU | 1.58 | 3.96 | 5.87 | |
| | | | | | | | | 19:00 | Rayo Zuliano-VEN | x | Athletico/PR-BRA | 8.75 | 4.82 | 1.33 | | | 19:00 | Sportivo Luqueno-PAR | x | Coquimbo-CHI | 2.20 | 3.39 | 3.22 | |
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